Dicyclohexyl{3-hydroxy-N′-[1-(2-oxidophenyl-κO)ethylidene]-2-naphthohydrazidato-κ2 N′,O}tin(IV)
نویسندگان
چکیده
In the title compound, [Sn(C(6)H(11))(2)(C(19)H(14)N(2)O(3))], the Sn(IV) atom is O,N,O' chelated by the deprotonated Schiff base ligand and exists in a cis-trigonal-bipyramidal environment, completed by the two cyclohexyl ligands.
منابع مشابه
(3-Hydroxy-2-{[1-(2-oxidophenyl)ethylidene]amino-κ2 O,N}propanoato-κO 1)diphenyltin(IV)
In the title compound, [Sn(C(6)H(5))(2)(C(11)H(11)NO(4))], the tin(IV) atom is penta-coordinated in a distorted trigonal-bipyramidal SnC(2)NO(2) geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers. Weak C-H⋯O inter-actions further link the dimers into chains extending in [010].
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The five-coordinate Sn(IV) atoms in the two crystallographically independent mol-ecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N'-[1-(5-chloro-2-oxidophen-yl)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazide, displays inter-molecular O-H⋯N hydrogen bondi...
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The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination. Both butyl chains and the naphth-yl-oxy portion are disordered over two sets of sites of equal occupancy.
متن کامل[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O]dibutyltin(IV)
The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination. One of the butyl chains is disordered over two sites in a 0.60 (1):0.40 (1) ratio.
متن کامل[N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O 2]diphenyltin(IV)
The Sn(IV) atom in the title compound, [Sn(C(6)H(5))(2)(C(18)H(11)ClN(2)O(3))], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C(2)SnNO(2) trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)°. Intra-molecular O-H⋯N hydrogen bonding is present in the crystal str...
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